@article { author = {Dgamaletdinovich Yambushev, Farid and Damirovna Khalikova, Fidaliya and Vasilevich Khalikov, Adel}, title = {Organometallic reactions of secondary arsingalogenides}, journal = {Eurasian Chemical Communications}, volume = {2}, number = {12}, pages = {1222-1227}, year = {2020}, publisher = {Sami Publishing Company (SPC)}, issn = {2717-0535}, eissn = {2676-6280}, doi = {10.22034/ecc.2020.121745}, abstract = {The experimental possibility of splitting asymmetric derivatives of three-and four-coordinated arsenic into optically active antipodes had for a long time remained unattainable for many well-known chemists, including Meisenheimer (Germany), Kamai (Russia), etc. When a racemic mixture of chiral arsines is cleaved with optically active components, a functional group (acidic or basic) is used that is contained in one of the fragments bound to the arsenic atom. Chiral arsines containing a carboxyl group are synthesized by oxidation of the corresponding fragments. Based on the results, to develop effective methods for the synthesis of tertiary arsines containing functional groups XC6H4(C2H5)AsC6H4У, where У=о-, m-, p-NH2, COOH, the reactivity of ethylarylarsine chlorides with organometallic compounds should be considered.}, keywords = {Alkyldiarylarsines,Ethylarylarsine Chlorides,Asymmetric,secondary,Tertiary Arsines,Carboxyphenylarsines,Chiral Arsines}, url = {https://www.echemcom.com/article_121745.html}, eprint = {https://www.echemcom.com/article_121745_9f106fa480b808b47ff8955e0f4bd3da.pdf} }