TY - JOUR ID - 121745 TI - Organometallic reactions of secondary arsingalogenides JO - Eurasian Chemical Communications JA - ECC LA - en SN - 2717-0535 AU - Dgamaletdinovich Yambushev, Farid AU - Damirovna Khalikova, Fidaliya AU - Vasilevich Khalikov, Adel AD - Department of Chemistry, Chemical Institute of Kazan Federal University, Russia Y1 - 2020 PY - 2020 VL - 2 IS - 12 SP - 1222 EP - 1227 KW - Alkyldiarylarsines KW - Ethylarylarsine Chlorides KW - Asymmetric KW - secondary KW - Tertiary Arsines KW - Carboxyphenylarsines KW - Chiral Arsines DO - 10.22034/ecc.2020.121745 N2 - The experimental possibility of splitting asymmetric derivatives of three-and four-coordinated arsenic into optically active antipodes had for a long time remained unattainable for many well-known chemists, including Meisenheimer (Germany), Kamai (Russia), etc. When a racemic mixture of chiral arsines is cleaved with optically active components, a functional group (acidic or basic) is used that is contained in one of the fragments bound to the arsenic atom. Chiral arsines containing a carboxyl group are synthesized by oxidation of the corresponding fragments. Based on the results, to develop effective methods for the synthesis of tertiary arsines containing functional groups XC6H4(C2H5)AsC6H4У, where У=о-, m-, p-NH2, COOH, the reactivity of ethylarylarsine chlorides with organometallic compounds should be considered. UR - https://www.echemcom.com/article_121745.html L1 - https://www.echemcom.com/article_121745_9f106fa480b808b47ff8955e0f4bd3da.pdf ER -