An efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition

Sajjadifar, Sami; Amini, Issa; Jabbari, Hadi; Pouralimardan, Omidali; Fekri, Mohammad Hossein; Pal, Kaushik

doi:10.33945/SAMI/ECC.2019.2.7

Document Type : Original Research Article

Authors

¹ Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran.

² Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran

³ Department of Chemistry, Payame Noor University, PO box 19395-3197, Tehran, Iran

⁴ Department of Chemistry, Ayatollah Alozma Borujerdi University, Borujerd, Iran.

⁵ Department of Nanotechnology, Bharath University,BIHER Research Park, Chennai, Tamil Nadu 600073, India

10.33945/SAMI/ECC.2019.2.7

Abstract

1-Methyl-3-(2-oxyethyl)-1H-Imidazol-3-ium-Borate Sulfonic Acid ([MOEI]-BSA) was easily prepared and used as a new and highly efficient solid acid catalyst for the synthesis of benzimidazole derivatives with high isolated yields. Various substituted benzimidazoles were synthesized by a combination of o-phenylenediamines and aldehydes in the presence of [MOEI]-BSA with excellent yields in water and under a mild and green reaction conditions. This method is also applicable for precursors such as aromatic and unsaturated aldehydes and o-phenylenediamines. Addition of organic part to BSA and synthesis of [MOEI]-BSA as a new Bronsted acidic ionic liquid (BAIL) improved the efficiency of this catalyst.
1-Methyl-3-(2-oxyethyl)-1H-Imidazol-3-ium-Borate Sulfonic Acid ([MOEI]-BSA) was easily prepared and used as a new and highly efficient solid acid catalyst for the synthesis of benzimidazole derivatives with high isolated yields. Various substituted benzimidazoles were synthesized by a combination of o-phenylenediamines and aldehydes in the presence of [MOEI]-BSA with excellent yields in water and under a mild and green reaction conditions. This method is also applicable for precursors such as aromatic and unsaturated aldehydes and o-phenylenediamines. Addition of organic part to BSA and synthesis of [MOEI]-BSA as a new Bronsted acidic ionic liquid (BAIL) improved the efficiency of this catalyst.

Graphical Abstract

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References

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Eurasian Chemical Communications

An efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition

References

References

Volume 1, Issue 2
March and April 2019
Pages 191-199

An efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition

References

References

Volume 1, Issue 2March and April 2019Pages 191-199

Volume 1, Issue 2
March and April 2019
Pages 191-199