Web of Science (Emerging Sources Citation Index), ISC

Document Type : Original Research Article

Authors

1 Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran

2 ResearchInstitute of Modern Biological Techniques (RIMBT), University of Zanjan, P O Box 45195-313, Zanjan, Iran

10.33945/SAMI/ECC.2020.3.11

Abstract

L-Proline is known as the most favored organocatalystin enamine-mediated reactions. Magnetic functionalization of this organocatalyst could solve its recovery and reuse problems. Herein we report the use of magnetic L-proline nano-biocatalyst for a simple and efficient one-pot coupling reaction of dimedone,malononitrile, and aromatic aldehydes to afford the corresponding tetrahydrobenzo[b]pyrans as a significant class of heterocyclic compounds with great biological and pharmacological importance according to a green protocol. Low cost, facile handling, simple preparation, highstability, reusability,and low toxicityare some remarkable features ofthis nano-biocatalyst.

Graphical Abstract

Magnetite L-proline as a reusable nano-biocatalyst for efficient synthesis of 4H-benzo[b]pyrans in water: a green protocol

Keywords

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