Efficient adsorption of heavy metal ions onto diethylamine functionalized calix[4]arene based silica resin

Junejo, Ranjhan; Memon, Shahabuddin; Palabiyik, Ismail Murat

doi:10.33945/SAMI/ECC.2020.7.6

Document Type : Original Research Article

Authors

¹ National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro-76080 / Pakistan

² Department of Analytical Chemistry, Faculty of Pharmacy, University of Ankara, Ankara, Turkey

10.33945/SAMI/ECC.2020.7.6

Abstract

Water might be contaminated by different metal ions, resulting in different water-borne diseases in human and aquatic life. This research study aimed at synthesizing the diethylamine functionalized calix[4]arene based silica (DFCS) resin for the effective removal of heavy metals such as Cd²⁺, Pb²⁺, and Hg²⁺from water. The DFCS resin was characterized using the FTIR spectroscopy and SEM techniques. The efficiency of the DFCS resin for the removal of metal ions was evaluated by performing equilibrium studies under the optimized conditions. Moreover, the experimental data were subjected to isotherm models; however, the Freundlich model was best-fit one as compared to the Langmuir model. The energy calculated from the D-R model was 10.3, 9.7 and 9.2 KJ/mol for Cd²⁺, Pb²⁺, and Hg²⁺,respectively, suggesting that the ion exchange process is involved. The thermodynamic values revealed that the reaction is spontaneous and exothermic, following the pseudo second-order kinetic model equation.

Graphical Abstract

Keywords

Main Subjects

Analytical chemistry

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Eurasian Chemical Communications

Efficient adsorption of heavy metal ions onto diethylamine functionalized calix[4]arene based silica resin

References

References

Volume 2, Issue 7
July 2020
Pages 785-797

Efficient adsorption of heavy metal ions onto diethylamine functionalized calix[4]arene based silica resin

References

References

Volume 2, Issue 7July 2020Pages 785-797

Volume 2, Issue 7
July 2020
Pages 785-797