H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

Rasooli, Mohsen; Zolfigol, Mohammad Ali; Moslemin, Mohammad Ali; Mohebat, Razieh; Chehardoli, Gholamabbas

doi:10.33945/SAMI/ECC.2020.1.5

Document Type : Original Research Article

Authors

¹ Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

² faculty of chemistry, bu-ali sina university, hamedan, iran

³ Department of Medicinal Chemistry, School of Pharmacy, Hamedan University of Medical Sciences

10.33945/SAMI/ECC.2020.1.5

Abstract

In the presence of {[K.18-Crown-6]X3}n (X= Br, I)-as interesting trihalide reagents, organic sulfides were oxidized to their corresponding sulfoxides using H2O2 as a green reagent. Via in situ generation of HOX, {[K.18-Crown-6]X3}n activates H2O2 and variously substituted sulfides were selectively transformed into the corresponding sulfoxides. We compared the obtained results of {[K.18-Crown-6]X3}n with some other organic tribromides. Unexpectedly, in most cases, the results were similar.

Graphical Abstract

Keywords

References

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Eurasian Chemical Communications

H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

References

References

Volume 2, Issue 1
January 2020
Pages 44-50

H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

References

References

Volume 2, Issue 1January 2020Pages 44-50

Volume 2, Issue 1
January 2020
Pages 44-50